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Oh my. I didn't realise that it's actually horrible for the person. Imagine grasping for air for 15 minutes! It must be horrible! That guy had a good reason to be scared of going away like that!
... And it's totally not an act made to stop this type of execution. It's not like hypoxia is undetectable by the body, as the gasping reflex is driven by rising levels of carbon dioxide in the lungs, not the lack of oxygen. Nor is it like the subject had any beef against the type of execution.
Come on. This is just fear mongering at this point
From the Wikipedia article on Inert Gas Asphyxiation:
tl;dr - literally everything that happened in the execution was precisely as expected. Smith did not suffer and was not conscious after the first few minutes of the procedure.
So this would be fine, but he did have symptoms consistent with hypercapnia, as described in the link you provided
They needed a larger breathable volume to diffuse the carbon dioxide present to keep the man from suffering.
They botched it.
Considering both include convulsions and cardiac arrest can be accompanied by agonal breathing, I don't think you can definitively state this.
Smith also resisted breathing for as long as he could at the beginning of the procedure and I think that needs to be taken into account. I won't say they absolutely didn't botch his execution, but I've yet to see any compelling evidence to that effect.
Unless they published their methodology, which they refused to do, we won't have any compelling evidence.