I haven't tried it, but I suppose you'll do just fine with debian sid. i.e edit /etc/apt/sources.list, swap $distro_nickname for sid, sudo apt update, sudo apt full-upgrade.
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It'll probably be fine, although I'd personally pick some rolling-release distro for better performance.
In any case, besides the release model I'm pretty sure a distribution you use doesn't matter that much. Usually every somewhat popular distro has the same few packages you need for games to work (32-bit libs, wine, steam, whatever).
Debian 12 and flatpak everything. I recently made the switch from Ubuntu and I couldn't be happier.
I think WINE recommend an up to date distro due to rapidly changing stuff needing up to date software and kernel. I think Debian wouldn't be great for that. I'd personally recommend OpenSuse. Rolling, up to date and great with KDE. Good luck.