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Occasional exposure isn't going to do much. Some people even use kerosene (diesel) can be used to wash some things off your hands. But you want to avoid it when possible.
Another reason I hate the EPA "safety" gas can nozzles. Because I've never felt more safe than when I'm covered in gasoline.
Generally, I'm all for things that limit emissions and improve safety. I always thought they were a PITA, but couldn't really be that much worse than the ones I see people use at the track usually.
I finally picked one up because it was all they had at the store, and holy shit those "safety tanks" are a nightmare by comparison. They spill so much fuel and after only a couple of years the seals on mine have gone bad and leak even more. I still would like to add a flame arrestor into the necks, but it amazes me at how awful they are.
I wholly understand why they exist and what all the safety features are for (preventing fuel from spilling if they're tipped/dropped, releasing fuel vapors, etc) but they seem utterly useless when I inevitably spill at least half a cup of fuel per 5 gal, just due to how poorly they're made.